Biotite

A K-rich subgroup of the trioctahedral mica group of the Mica Group. The CNMMN Subcommittee on Nomenclature of the Micas (1998, 1999) has recommended that the name biotite be used for any minerals in the “series” between the joins Annite-Phlogopite and Siderophyllite-Eastonite, and is therefore no longer to be regarded as a species name, more strictly a subgroup. Other closely related species such as Fluorophlogopite and Fluorotetraferriphlogopite are usually included in the subgroup. The name is most commonly used generically (in the field or petrologically) for any unanalysed or incompletely analysed dark-coloured, Fe-rich micas, including Annite, Fluorannite, Tetra-ferri-annite and Siderophyllite. Commonly alters to vermiculite or chlorite, and these may be intimately interlayered. Rock-forming biotite may be confused with stilpnomelane.

History

Activities related to discovery and approval of the group members

Structural context

a5.35.357 (5.3327)
b5.39.268 (9.1078)
c10.10260 (13.7288)
alpha90
beta90100.3 (98.8609)
gamma90120 (90.9677)
volume487.3561459.6 (621.2472)

Based on 31 measurements

Chemical context

Stoichiometric formulas

Biotite
mindat.org
  • Sept. 6, 2023K(Fe2+/Mg)2(Al/Fe3+/Mg/Ti)([Si/Al/Fe]2Si2O10)(OH/F)2A slash in the formula indicates different elements can occur in this position but without assumption on priority.
  • March 13, 2023K(Fe2+/Mg)2(Al/Fe3+/Mg/Ti)([Si/Al/Fe]2Si2O10)(OH/F)2 or Simplified: K(Mg,Fe)3AlSi3O10(OH)2Simplified formula more commonly used is based on the more common species regarded as 'biotite' subgroup. A slash in the formula indicates different elements can occur in this position but without assumption on priority.

Elements recorded on EPMA

31
Al
31
K
31
Mg
31
O
31
Si
28
Fe
22
Ti
17
Na
15
H
10
Ca
10
Mn
8
Cr
4
F
2
Ba
1
Cl

Physical properties

Luminescence
None